Effect
of π‑Spacer Length in Novel Xanthene-Linked l‑(D−π–A)2‑Type
Dianchoring Dyes for Dye-Sensitized Solar Cells
Posted on 2022-06-01 - 16:05
The
effect of thiophene π-spacer length was studied in xanthene-linked l-(D−π–A)2-type dianchoring dye
performance in dye-sensitized solar cells. The photophysical, electrochemical,
and photovoltaic performances of KS-19 with single thiophene
and KS-21 with dithiophene units as π-spacers were
compared. The overall result showed that the presence of an extra
thiophene unit in KS-21 led to the extension of conjugation,
causing broadening and a red-shift of light absorption which in turn
resulted in increased JSC and power conversion
efficiency (PCE).
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Baptayev, Bakhytzhan; Kim, Se-Mi; Bolatbek, Bexultan; Lee, Sang Hee; Balanay, Mannix P. (2022). Effect
of π‑Spacer Length in Novel Xanthene-Linked l‑(D−π–A)2‑Type
Dianchoring Dyes for Dye-Sensitized Solar Cells. ACS Publications. Collection. https://doi.org/10.1021/acsaem.2c00384