Directed
γ‑C(sp3)–H
Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox
Catalysis

Rovis, Tomislav

Directed γ‑C(sp³)–H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis

Posted on 2017-10-12 - 13:56

Visible light photoredox catalysis enables direct γ- C(sp³)–H alkylation of saturated aliphatic carbonyl compounds. Electron-deficient alkenes are used as the coupling partners in this reaction. Distinguished site selectivity is controlled by the predominant 1,5-hydrogen atom transfer of an amidyl radical generated in situ.

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Chen, Dian-Feng; C. K. Chu, John; Rovis, Tomislav (2017). Directed γ‑C(sp³)–H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis. ACS Publications. Collection. https://doi.org/10.1021/jacs.7b09306

https://doi.org/10.1021/jacs.7b09306

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