Diaziridyl Ether of Bisphenol A
Posted on 2018-05-18 - 19:40
Increased
complexities in applications involving curable materials
virtually need new materials that can overcome the limitations of
existing ones. Resins, the structure of which is based on bisphenol
A backbone terminated with three membered N-heterocyclesaziridineshave
been synthesized, and their thermal-curing performance in solution
and solid state was evaluated by NMR and FT-IR spectroscopies, differential
scanning calorimetry, and single lap shear strength test and compared
with that of analogous epoxy resin (diglycidyl ether of bisphenol
A; DGEBA). Results reveal that the chemical reactivity of the aziridine-based
resins is fine-tunable by controlling the N-substituent
of aziridine. These resins can undergo ring-opening polymerization
in the presence of various curing agents under unprecedentedly mild
conditions and show remarkably rapid curing rate, wide substrate scope,
and excellent chemoselectivity as compared to the analogous epoxy
resin. Our results demonstrate superb curing ability of aziridine,
making it promising for applications in materials and polymer sciences.
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Kang, Seohyun; Moon, Hyun Kyung; Yoon, Hyo Jae (2018). Diaziridyl Ether of Bisphenol A. ACS Publications. Collection. https://doi.org/10.1021/acs.macromol.8b00550
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AUTHORS (3)
SK
Seohyun Kang
HM
Hyun Kyung Moon
HY
Hyo Jae Yoon