Designed Construction of Cluster Organic Frameworks
from Lindqvist-type Polyoxovanadate Cluster

Yang, Guo-Yu

Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster

Posted on 2018-08-09 - 20:29

Two unprecedented examples of cluster organic frameworks (TBA)₃Cu[V₆O₁₃(L)₂]₂·4DEF (2) (TBA)Ag[V₆O₁₃(L)₂] solvent (3) (TBA = tetrabutylammonium, H₃L = tris(hydroxymethyl)-4-picoline, DEF = N,N′-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.

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Li, Xin-Xiong; Zhang, Lin-Jie; Cui, Cai-Yan; Wang, Rui-Hu; Yang, Guo-Yu (2018). Designed Construction of Cluster Organic Frameworks from Lindqvist-type Polyoxovanadate Cluster. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b01528

https://doi.org/10.1021/acs.inorgchem.8b01528

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