Copper-Catalyzed ipso-Borylation
of Fluoroarenes
Version 2 2017-06-17, 13:29
Version 1 2017-06-08, 16:19
Posted on 2017-06-17 - 13:29
ipso-Borylation of fluoroarenes has been achieved
using an air-stable copper complex as a catalyst. Mechanistic studies
suggest that the reaction proceeds via an SRN1 mechanism
involving a single-electron-transfer (SET) process and not via the
typical SNAr mechanism. This method differs from the previously
reported nickel/copper-cocatalyzed system in terms of scope of the
substrate and has exhibited good scalability. Double and triple ipso-borylations of several di- and trifluoroarenes have
been also achieved efficiently, enhancing the synthetic utility of
this method.
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Niwa, Takashi; Ochiai, Hidenori; Hosoya, Takamitsu (2017). Copper-Catalyzed ipso-Borylation
of Fluoroarenes. ACS Publications. Collection. https://doi.org/10.1021/acscatal.7b01448
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AUTHORS (3)
TN
Takashi Niwa
HO
Hidenori Ochiai
TH
Takamitsu Hosoya