Copper-Catalyzed Borylative Cyclization of in Situ
Generated o‑Allenylaryl Nitriles with Bis(pinacolato)diboron
Posted on 2017-06-26 - 22:46
A Cu-catalyzed cascade
borylcupration/cyclization of in situ generated
allene-nitriles with B2pin2 has been developed,
which provides highly substituted 3-boryl-1-naphthylamines with
excellent regioselectivity and wide functional group compatibility.
It has been shown that, for the first time, the catalytically generated
allylcopper species can be captured by a cyano group from a normal
nitrile to furnish a carbocycle.
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Xiong, Meijun; Xie, Xin; Liu, Yuanhong (2017). Copper-Catalyzed Borylative Cyclization of in Situ
Generated o‑Allenylaryl Nitriles with Bis(pinacolato)diboron. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b01355
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