Coordination-Driven Self-Assembly of Supramolecular Cages:
Heteroatom-Containing and Complementary Trigonal Prisms
Posted on 2003-07-18 - 00:00
The self-assembly of three nanoscopic prisms of approximate size 1 × 4 nm is reported.
Tetrahedral carbon, silicon, and phosphorus were used as structure-defining elements in these coordination-based cages. A carbon-based assembly completes a pair of nanoscopic complementary 3-D structures.
The formation of the structures is supported by multinuclear NMR, ESI FT-ICR mass spectrometry, and
elemental analysis data.
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Kryschenko, Yury K.; Seidel, S. Russell; Muddiman, David C.; Nepomuceno, Angelito I.; Stang, Peter J. (2016). Coordination-Driven Self-Assembly of Supramolecular Cages:
Heteroatom-Containing and Complementary Trigonal Prisms. ACS Publications. Collection. https://doi.org/10.1021/ja030209n