Construction of Chiral 1,3-Diamines through Rhodium-Catalyzed
Asymmetric Arylation of Cyclic N‑Sulfonyl
Imines
Posted on 2019-06-19 - 19:14
A rhodium/sulfur–olefin
complex catalyzed asymmetric 1,2-addition
of arylboronic acids to six-membered 1,2,6-thiadiazinane 1,1-dioxide-type
cyclic imines to access highly optically active sulfamides (95–99%
ee) has been developed. By taking advantage of the simple functional
group transformations, an interesting array of valuable chiral 1,3-diamines
with different substitution patterns can be readily obtained in a
highly enantioenriched manner.
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Wu, Chun-Yan; Xu, Ming-Hua (2019). Construction of Chiral 1,3-Diamines through Rhodium-Catalyzed
Asymmetric Arylation of Cyclic N‑Sulfonyl
Imines. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.9b01633
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