Chiral Phosphoric Acid Catalyzed Asymmetric Oxidative
Dearomatization of Naphthols with Quinones

Wang, Rui

Chiral Phosphoric Acid Catalyzed Asymmetric Oxidative Dearomatization of Naphthols with Quinones

Version 2 2016-10-17, 14:00

Version 1 2016-09-30, 20:04

Posted on 2016-09-30 - 00:00

A highly enantioselective oxidative dearomatization of naphthols with quinones catalyzed by a chiral spirocyclic phosphoric acid is described. The strategy provides concise access to enantioenriched cyclohexadienones with a quinone moiety. Remarkably, the obtained products could be easily transformed to a potentially useful dihydronaphtho[2,1-b]benzofuran scaffold.

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Zhu, Gongming; Bao, Guangjun; Li, Yiping; Yang, Junxian; Sun, Wangsheng; Li, Jing; et al. (2016). Chiral Phosphoric Acid Catalyzed Asymmetric Oxidative Dearomatization of Naphthols with Quinones. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.6b02609

https://doi.org/10.1021/acs.orglett.6b02609

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