Catalytic
Hydrothiolation: Regio- and Enantioselective
Coupling of Thiols and Dienes
Posted on 2018-08-09 - 18:49
We report a Rh-catalyzed hydrothiolation
of 1,3-dienes, including
petroleum feedstocks. Either secondary or tertiary allylic sulfides
can be generated from the selective addition of a thiol to the more
substituted double bond of a diene. The catalyst tolerates a wide
range of functional groups, and the loading can be as low as 0.1 mol
%.
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Yang, Xiao-Hui; Davison, Ryan T.; Dong, Vy M. (2018). Catalytic
Hydrothiolation: Regio- and Enantioselective
Coupling of Thiols and Dienes. ACS Publications. Collection. https://doi.org/10.1021/jacs.8b06957
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AUTHORS (3)
XY
Xiao-Hui Yang
RD
Ryan T. Davison
VD
Vy M. Dong