Breaking Carbon–Chlorine Bonds with the Unconventional
Lewis Acid Dodecachlorocyclohexasilane
Posted on 2018-11-08 - 20:48
c-Si6Cl12 functions
as a Lewis acid strong enough to abstract chloride ions from 2 mol
of triphenylchloromethane to form the salt [Tr+]2[Si6Cl142–]. This is the
first example of a Lewis acid “hole” breaking a carbon–halogen
bond.
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Frohlich, Matthew
T.; Anderson, Kenneth J.; Ugrinov, Angel; Boudjouk, Philip (2018). Breaking Carbon–Chlorine Bonds with the Unconventional
Lewis Acid Dodecachlorocyclohexasilane. ACS Publications. Collection. https://doi.org/10.1021/acs.inorgchem.8b00631
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AUTHORS (4)
MF
Matthew
T. Frohlich
KA
Kenneth J. Anderson
AU
Angel Ugrinov
PB
Philip Boudjouk