Borane-Catalyzed Transfer Hydrogenations of Pyridines
with Ammonia Borane

Du, Haifeng

Borane-Catalyzed Transfer Hydrogenations of Pyridines with Ammonia Borane

Version 2 2016-10-17, 14:01

Version 1 2016-09-28, 17:53

Posted on 2016-09-28 - 00:00

With the use of ammonia borane as a hydrogen source, a borane catalyzed metal-free transfer hydrogenation of pyridines was successfully realized for the first time to furnish a variety of piperidines in 44–88% yields with moderate to excellent cis-selectivities. The ease in handling without requiring high pressure H₂ makes this transfer hydrogenation practical and useful.

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Zhou, Qiwen; Zhang, Lanqiong; Meng, Wei; Feng, Xiangqing; Yang, Jing; Du, Haifeng (2016). Borane-Catalyzed Transfer Hydrogenations of Pyridines with Ammonia Borane. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.6b02610

https://doi.org/10.1021/acs.orglett.6b02610

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