Anionic N-Fries Rearrangement of
N-Carbamoyl Diarylamines to
Anthranilamides. Methodology and
Application to Acridone and
Pyranoacridone Alkaloids

Snieckus, Victor

Anionic N-Fries Rearrangement of N-Carbamoyl Diarylamines to Anthranilamides. Methodology and Application to Acridone and Pyranoacridone Alkaloids

Posted on 2006-03-16 - 00:00

A general alkyllithium/LDA-mediated rearrangement of N-carbamoyl diarylamines 7a−g into the anthranilamides 8a−g and 9a−g (Table ) is presented and applied to a regioselective efficient construction of acridone (17) and pyranoacridone (18) alkaloids (Scheme ).

CITE THIS COLLECTION

MacNeil, Stephen L.; J. Wilson, Brian; Snieckus, Victor (2016). Anionic N-Fries Rearrangement of N-Carbamoyl Diarylamines to Anthranilamides. Methodology and Application to Acridone and Pyranoacridone Alkaloids. ACS Publications. Collection. https://doi.org/10.1021/ol053162e

https://doi.org/10.1021/ol053162e

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