A New Decaoxidooctaborate(2−) Anion, [B8O10(OH)6]2–: Synthesis
and Characterization of [Co(en)3][B5O6(OH)4][B8O10(OH)6)]·5H2O (en = 1,2-Diaminoethane)
Posted on 2015-01-20 - 00:00
The synthesis and
X-ray diffraction structure of [Co(en)3][B5O6(OH)4][B8O10(OH)6]·5H2O (1) are reported. Compound 1 arises through a selective-templating process from a Dynamic
Combinatorial Library of polyborate anions. Compound 1 contains two different polyborate species, with [B8O10(OH)6]2– being particularly
novel. It is comprised of fused tetraborate and pentaborate anions
with a 4-coordinate B atom and a 3-coordinate O atom in common.
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Altahan, Mohammed
A.; Beckett, Michael A.; Coles, Simon
J.; Horton, Peter N. (2016). A New Decaoxidooctaborate(2−) Anion, [B8O10(OH)6]2–: Synthesis
and Characterization of [Co(en)3][B5O6(OH)4][B8O10(OH)6)]·5H2O (en = 1,2-Diaminoethane). ACS Publications. Collection. https://doi.org/10.1021/ic5027834
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