2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO:  Highly Efficient
Organocatalysts for Oxidation of Alcohols

Iwabuchi, Yoshiharu

2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols

Posted on 2006-07-05 - 00:00

Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl compounds in excellent yields.

CITE THIS COLLECTION

Shibuya, Masatoshi; Tomizawa, Masaki; Suzuki, Iwao; Iwabuchi, Yoshiharu (2016). 2-Azaadamantane N-Oxyl (AZADO) and 1-Me-AZADO: Highly Efficient Organocatalysts for Oxidation of Alcohols. ACS Publications. Collection. https://doi.org/10.1021/ja0620336

https://doi.org/10.1021/ja0620336

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