1,2-Dihydro-1,2-oxaborine:  A Boron−Oxygen Heterocycle
Isoelectronic with Benzene

Ashe, Arthur J.

1,2-Dihydro-1,2-oxaborine: A Boron−Oxygen Heterocycle Isoelectronic with Benzene

Posted on 2020-04-03 - 11:44

1,2-Dihydro-2-phenyl-1,2-oxaborine (1b) has been prepared by the reaction of (2,3-dihydro-1,2-oxaborol-3-yl)potassium (8) with methylene chloride and KN(SiMe₃)₂. Structural characterization of the phenyl−Cr(CO)₃ complex 9 suggests that the 1,2-dihydro-1,2-oxaborine ring has a π-delocalized structure.

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Chen, Jinhui; Bajko, Zoltan; Kampf, Jeff W.; Ashe, Arthur J. (2007). 1,2-Dihydro-1,2-oxaborine: A Boron−Oxygen Heterocycle Isoelectronic with Benzene. ACS Publications. Collection. https://doi.org/10.1021/om070113s

https://doi.org/10.1021/om070113s

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