1,2-Benzothiazines from Sulfoximines and Allyl Methyl
Carbonate by Rhodium-Catalyzed Cross-Coupling and Oxidative Cyclization
Posted on 2017-03-24 - 13:35
4-Unsubstituted 1,2-benzothiazines
are prepared from sulfoximines
and allyl methyl carbonate by Rh(III)-catalyzed domino allylation/oxidative
cyclization. A wide range of functional groups on the sulfoximine
are tolerated. A plausible mechanism is proposed, and chemical modifications
of the products have been explored.
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Wen, Jian; Tiwari, Deo Prakash; Bolm, Carsten (2017). 1,2-Benzothiazines from Sulfoximines and Allyl Methyl
Carbonate by Rhodium-Catalyzed Cross-Coupling and Oxidative Cyclization. ACS Publications. Collection. https://doi.org/10.1021/acs.orglett.7b00488
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AUTHORS (3)
JW
Jian Wen
DT
Deo Prakash Tiwari
CB
Carsten Bolm