jp1c08569_si_003.mp4 (4.94 MB)
Azo(xy) vs Aniline Selectivity in Catalytic Nitroarene Reduction by Intermetallics: Experiments and Simulations
mediaposted on 2021-10-27, 18:45 authored by Carena L. Daniels, Da-Jiang Liu, Marquix A. S. Adamson, Megan Knobeloch, Javier Vela
Intermetallic nanoparticles are promising catalysts in hydrogenation and fuel cell technologies. Much is known about the ability of intermetallic nanoparticles to selectively reduce nitro vs alkene, alcohol, or halide functional groups; less is known about their selectivity toward aniline vs azo or azoxy condensation products that result from the reduction of a nitro group alone. Because azo(xy)arenes bear promise as dyes, chemical stabilizers, and building blocks to functional materials but can be difficult to isolate, developing high surface area nanoparticle catalysts that display azo(xy) selectivity is desirable. To address this question, we studied a family of nanocrystalline group 10 metal (Pd, Pt)- and group 14 metal (Ge, Sn, Pb)-containing intermetallicsPd2Ge, Pd2Sn, Pd3Sn2, Pd3Pb, and PtSnin the catalytic reduction of nitroarenes. In contrast to monometallic Au, Pt, and Pd nanoparticles and ″random″ PdxSn1 – x nanoalloys, which are selective for aniline, nanoparticles of atomically precise intermetallic Pd2Ge, Pd2Sn, Pd3Sn2, and PtSn prefer an indirect condensation pathway and have a high selectivity for the azo(xy) products. The only exception is Pd3Pb, the most active among the intermetallic nanoparticles studied here, which is instead selective for aniline. Employing a novel application of molecular dynamicsbased on machine learned potentials within a DeePMD frameworkto heterogeneous catalysis, we are able to identify key reaction species on the different types of catalysts employed, furthering our understanding of the unique selectivity of these materials. By demonstrating how intermetallic nanoparticles can be as active yet more selective than other more traditional catalysts, this work provides new physical insights and opens new opportunities in the use of these materials in other important chemical transformations and applications.
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