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p-Tolylsulfinyl Amides:  Reagents for Facile Electrophilic Functionalization of Olefins

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journal contribution
posted on 02.04.2004, 00:00 by Larissa B. Krasnova, Andrei K. Yudin
A variety of olefins were found to react with sulfinyl amides in the presence of POCl3 to give β-chlorosulfides and β-hydroxysulfides in good yields. In the absence of nucleophiles, p-tolylsulfinyl amides were found to react with olefins with the formation of allylsulfoxides.