Water-in-Acid Gel Polymer Electrolyte Realized through a Phosphoric Acid-Enriched Polyelectrolyte Matrix toward Solid-State Supercapacitors
journal contributionposted on 2018-08-21, 00:00 authored by Vidyanand Vijayakumar, Meena Ghosh, Arun Torris A. T., Nikhil Chandran M. K., Sanoop B. Nair, Manohar V. Badiger, Sreekumar Kurungot
A new concept of water-in-acid gel polymer electrolytes (GPEs) is introduced. The simple and scalable UV-light-assisted synthesis of a copolymer matrix possessing polyelectrolyte behavior, followed by swelling in minimally diluted H3PO4 (15.1 M/88 wt % aqueous solution), effects formation of a high proton-conducting, self-standing, and mechanically stable polyelectrolyte GPE (PGPE). Retention of high mechanical stability despite the presence of a large amount of liquid species makes it a promising candidate for replacing conventional GPEs. The high proton conductivity (9.8 × 10–2 S cm–1) of the PGPE at an ambient temperature of 303 K is attributed to the high concentration of the conducting species present in the polymer matrix. The PGPE-based polyaniline (PANI) supercapacitor device (PANI-1) with a mass loading of 1 mg cm–2 exhibits a high specific gravimetric capacitance of 385 F g–1 at a current density of 0.25 mA cm–2. At the same current density, the PANI-5 device retains high gravimetric and areal capacitance values of 258 F g–1 and 1288 mF cm–2, respectively. The low equivalent series resistance value of 0.78 Ω (for the PANI-5 device) further proves the excellent electrode–electrolyte interface formed by the water-in-acid GPE. A 100% capacitance retention even after 9000 continuous charge–discharge cycles strongly indicates the feasibility of adopting water-in-acid GPEs in future supercapacitors.
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0.78 Ωfuture supercapacitorsdensitymass loadingequivalent series resistance valueSolid-State Supercapacitorswater-in-acid GPEPhosphoric Acid-Enriched Polyelectrolyte Matrixcopolymer matrixpolyelectrolyte GPEambient temperatureWater-in-Acid Gel Polymer Electrolyte RealizedPOPGPE-based polyanilinescalable UV-light-assisted synthesiscmpolyelectrolyte behavior303 Kareal capacitance valueswater-in-acid GPEspolymer matrixspeciessupercapacitor devicegravimetric capacitancePANIwater-in-acid gel polymer electrolytes