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Visible-Light Enabled C(sp3)–C(sp2) Cross-Electrophile Coupling via Synergistic Halogen-Atom Transfer (XAT) and Nickel Catalysis

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journal contribution
posted on 2022-03-31, 20:05 authored by Girish Suresh Yedase, Avishek Kumar Jha, Veera Reddy Yatham
We herein report the first visible-light-mediated cross-coupling of unactivated alkyl iodides with aryl bromides through synergistic halogen atom transfer (XAT) and nickel catalysis. This simple protocol operates under mild reaction conditions and tolerates a variety of functional groups affording C­(sp3)–C­(sp2) cross-coupling products in good to moderate yields.