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Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands

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journal contribution
posted on 17.01.2017, 13:40 by Andrew Brown, Mohamed Saber, Willem Van den Heuvel, Kelsey Schulte, Alessandro Soncini, Kim R. Dunbar
The titanium­(III) cyanide compound [Et4N]­[Tp*Ti­(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.