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Synthesis of the Putative Structure of (±)-Amarbellisine

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journal contribution
posted on 2013-01-18, 00:00 authored by Dandan Liu, Jingbo Chen, Long Ai, Hongbin Zhang, Jianping Liu
The title compound was synthesized mainly by palladium catalytic coupling, cyclopropyl ring-opening rearrangement, epoxidation, Swern oxidation, demethanol reactions, and selective reduction. This synthesis was achieved in 16 steps with 9.7% overall yield. Unfortunately, the published spectroscopic data do not match with those of our synthetic compound.