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Synthesis of 3,5-Disubstituted BODIPYs Bearing N‑Containing Five-Membered Heteroaryl Groups via Nucleophilic C–N Bond Formation

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journal contribution
posted on 10.04.2018, 00:00 by Takaharu Satoh, Kaori Fujii, Yoshifumi Kimura, Yoshihiro Matano
Aromatic substitution reactions were applied to the divergent synthesis of a series of symmetrically and unsymmetrically 3,5-disubstituted BODIPYs bearing N-heteroaryl groups. Furthermore, the effect of N-heteroaryl substituents at the 3- and 5-positions on the optical and photophysical properties of the BODIPY π-electron system was elucidated.