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Supramolecular Lone Pair−π/π−π/π−Anion Assembly in a Mg(II)−Malonate−2-Aminopyridine−Nitrate Ternary System

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journal contribution
posted on 2009-02-26, 00:00 authored by Somnath Ray Choudhury, Biswajit Dey, Suranjana Das, Patrick Gamez, Arturo Robertazzi, Kai-Ting Chan, Hon Man Lee, Subrata Mukhopadhyay
The solid-state structure of an alkaline-earth metal complex reveals the formation of a remarkable supramolecular framework based on concurrent lone pair−π, π−π, and π−anion interactions whose stability has been investigated by density functional theory.