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Stereoselective RhI-Catalyzed Tandem Conjugate Addition of Boronic Acids−Michael Cyclization

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journal contribution
posted on 2008-01-17, 00:00 authored by Cristina Navarro, Aurelio G. Csákÿ
The first examples of the stereoselective sequence RhI-catalyzed tandem conjugate addition of boronic acids to enones−Michael cyclization, is reported. The reaction is carried out in dioxane−H2O at rt, and 1,2,3-trisubstituted indans are obtained in a highly regio- and stereoselective fashion.

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