om9801251_si_001.pdf (1.39 MB)
Reactions of Azines with Titanocene: C−H Activation, C−C Coupling, and N−N Cleavage to Heterobimetallic Complexes
journal contribution
posted on 1998-04-04, 00:00 authored by Andreas Ohff, Thorsten Zippel, Perdita Arndt, Anke Spannenberg, Rhett Kempe, Uwe RosenthalEither C−H activation or C−C coupling is
observed in reactions of titanocene with azines
(R1R2CN−NCR1R2),
which lead to the formation of
complexes 2 and 3, respectively. The
reaction with two
different metallocene units can yield heterobimetallic
bis(alkylideneamido) complexes (4).