ol036330g_si_002.pdf (138.26 kB)
Preparation and Coordination Properties Including Catalytic Activities of a Bulky 2-Methyl-3-thioxo-1,3-diphosphapropene
journal contributionposted on 2004-02-05, 00:00 authored by Hongze Liang, Shigekazu Ito, Masaaki Yoshifuji
2-Methyl-3,3-diphenyl-3-thioxo-1-(2,4,6-tri-tert-butylphenyl)-1,3-diphosphapropene, which bears a PC−PS skeleton, was prepared and used as a ligand of transition-metal complexes. The palladium complexes containing the ligated 3-thioxo-1,3-diphophapropene were stable and used for catalytic reactions such as cross-couplings and direct conversion of allyl alcohol to allylaniline.