ol6b02563_si_001.pdf (2.26 MB)
Download file

Metal-Free Visible-Light-Mediated Oxidative Cross-Coupling of Thiols with P(O)H Compounds Using Air as the Oxidant

Download (2.26 MB)
journal contribution
posted on 13.09.2016, 12:34 authored by Jian-Guo Sun, Hua Yang, Ping Li, Bo Zhang
Visible light along with 5 mol % of rose bengal catalyzes the direct S–P­(O) coupling between thiols and P­(O)H compounds in the presence of air as the green oxidant. The protocol is operationally simple and amenable to gram-scale synthesis. A variety of S–P­(O) coupling products can be readily prepared in moderate to excellent yields. The reaction features good functional-group tolerance, operational simplicity, and excellent practicality.

History