ol6b03681_si_001.pdf (7.38 MB)
Download file

Metal-Free C–H Functionalization of Alkanes by Aryldiazoacetates

Download (7.38 MB)
journal contribution
posted on 07.02.2017, 15:05 by Cecilia Tortoreto, Daniel Rackl, Huw M. L. Davies
Thermally induced reactions of donor/acceptor diazo compounds generate carbene intermediates capable of C–H functionalization reactions of alkanes. A variety of C–H insertion products were obtained in moderate to good yields and in certain cases with good site selectivity, favoring the functionalization of the more highly substituted C–H bond.

History