nl1c04389_si_001.pdf (2.02 MB)

MXene-Based Aerogel Anchored with Antimony Single Atoms and Quantum Dots for High-Performance Potassium-Ion Batteries

Download (2.02 MB)
journal contribution
posted on 2022-01-19, 21:06 authored by Xin Guo, Hong Gao, Shijian Wang, Guang Yang, Xiuyun Zhang, Jinqiang Zhang, Hao Liu, Guoxiu Wang
Rationally electronic structure engineering of nanocomposite electrodes shows great promise for enhancing the electrochemical performance of rechargeable batteries. Herein, we report antimony single atoms and quantum dots (∼5 nm) codecorated Ti3C2Tx MXene-based aerogels (Sb SQ@MA) for high-performance potassium-ion batteries (PIBs). We found that the atomically dispersed Sb could modify the electronic structure of the Sb/Ti3C2Tx composite, improve the charge transfer kinetics, and enhance the potassium storage capability at the heterointerfaces. Additionally, the MXene-based aerogel with rich surface functional groups and defects provides abundant anchoring sites and endows the composite reinforced structural stability and highly efficient electron transfer. The high loading of Sb (∼60.3 wt %) with short ionic transport pathways is desired potassium reservoirs. These features synergistically enhance the rate and cycling performance of the Sb SQ@MA electrodes in PIBs. This work has demonstrated an enlightening technique to tailor the interface activity of heterostructured electrodes for electrochemical applications.