jz2c00274_si_001.pdf (7.08 MB)
Highly Mobile Excitons in Single Crystal Methylammonium Lead Tribromide Perovskite Microribbons
journal contributionposted on 2022-04-19, 16:12 authored by Luke McClintock, Ziyi Song, H. Clark Travaglini, R. Tugrul Senger, Vigneshwaran Chandrasekaran, Han Htoon, Dmitry Yarotski, Dong Yu
Excitons are often given negative connotation in solar energy harvesting in part due to their presumed short diffusion lengths. We investigate exciton transport in single-crystal methylammonium lead tribromide (MAPbBr3) microribbons via spectrally, spatially, and temporally resolved photocurrent and photoluminescence measurements. Distinct peaks in the photocurrent spectra unambiguously confirm exciton formation and allow for accurate extraction of the low temperature exciton binding energy (39 meV). Photocurrent decays within a few μm at room temperature, while a gate-tunable long-range photocurrent component appears at lower temperatures (about 100 μm below 140 K). Carrier lifetimes of 1.2 μs or shorter exclude the possibility of the long decay length arising from slow trapped-carrier hopping. Free carrier diffusion is also an unlikely source of the highly nonlocal photocurrent, due to their small fraction at low temperatures. We attribute the long-distance transport to high-mobility excitons, which may open up new opportunities for novel exciton-based photovoltaic applications.
temporally resolved photocurrentsolar energy harvestingphotocurrent decays withinhighly nonlocal photocurrentbased photovoltaic applications39 mev ).140 k ).highly mobile excitonsfree carrier diffusioninvestigate exciton transportnovel excitonmobility excitonsdistance transportcarrier lifetimescarrier hoppingunlikely sourcesmall fractionslow trappedshorter excluderoom temperaturephotoluminescence measurementsnew opportunitiesmay openlower temperatureslow temperaturesdistinct peaksaccurate extraction2 μs