Gas-Phase Preparation of Subvalent Germanium Monoxide (GeO, X¹Σ⁺) via Non-Adiabatic Reaction Dynamics in the Exit Channel

The subvalent germanium monoxide (GeO, X¹Σ⁺) molecule has been prepared via the elementary reaction of atomic germanium (Ge, ³P_j) and molecular oxygen (O₂, X³Σ_g^–) with each reactant in its electronic ground state by means of single-collision conditions. The merging of electronic structure calculations with crossed beam experiments suggests that the formation of germanium monoxide (GeO, X¹Σ⁺) commences on the singlet surface through unimolecular decomposition of a linear singlet collision complex (GeOO, i1, C_∞v, ¹Σ⁺) via intersystem crossing (ISC) yielding nearly exclusively germanium monoxide (GeO, X¹Σ⁺) along with atomic oxygen in its electronic ground state [p1, O­(³P)]. These results provide a sophisticated reaction mechanism of the germanium–oxygen system and demonstrate the efficient “heavy atom effect” of germanium in ISC yielding (nearly) exclusive singlet germanium monoxide and triplet atomic oxygen compared to similar systems (carbon dioxide and dinitrogen monoxide), in which non-adiabatic reaction dynamics represent only minor channels.