We found that the
write-once-read-many-times (WORM, inerasable)-to-rewritable
(erasable) transition phenomenon results from the different structures
of the filament, which is determined by the grain orientations of
the deposited films. The conduction mechanism of this switching transition
and its impact on the synaptic behavior in various ZnO nanostructures
are also discussed. Furthermore, our WORM devices have a programmable
physical damage function that can be exploited for use in security
systems against data theft, hacking, and unauthorized use of software/hardware.
This work proposes ZnO-based nonvolatile memory for invisible electronic
applications and gives valuable insight into the design of WORM and
rewritable memories.