Experimental Study on the Kinetics of CO₂ and H₂O Adsorption on Honeycomb Carbon Monoliths under Cement Flue Gas Conditions

The main challenge of adsorption consists in the production of materials that can be used in real situations. This study comprehensively describes the CO₂ and H₂O adsorption behavior of honeycomb-shaped sorbents commonly used in rapid pressure swing adsorption cycles (RPSA). With this purpose, the kinetics and equilibrium of adsorption of CO₂/H₂O/N₂ mixtures on three honeycomb carbon monoliths (793, 932, and AM03) were assessed in a thermogravimetric analyzer (TGA) under different postcombustion capture scenarios (temperature of 50 °C and several concentrations of CO₂). The kinetics study exhibited that the single adsorption of CO₂ and H₂O can be adequately described by the Avrami and exponential decay-2 models, respectively. As expected, the three carbon monoliths presented fast adsorption of CO₂ from a CO₂/H₂O mixture. Furthermore, when humid flue gas was considered, overall adsorption kinetics were governed by CO₂. Besides, the experimental data fitting to the intraparticle diffusion model showed that gradual CO₂ and H₂O diffusion toward the micropores was the rate-limiting stage. The obtained results give a better insight into the selective adsorption of CO₂ and the potential of honeycomb carbon monoliths to separate CO₂ from humid flue gas in the context of the cement industry. Carbon monolith 793 is the best carbon monolith candidate to capture CO₂ under the evaluated conditions: a capacity of adsorption of 1 mmol of CO₂ g^–1 and favorable kinetics in 32 vol % CO₂ and 4 vol % H₂O_(v), at 50 °C and 101.3 kPa.