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Enantioselective Chromatographic Resolution and One-Pot Synthesis of Enantiomerically Pure Sulfoxides over a Homochiral Zn−Organic Framework

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journal contribution
posted on 31.10.2007, 00:00 authored by Alexey L. Nuzhdin, Danil N. Dybtsev, Konstantin P. Bryliakov, Evgenii P. Talsi, Vladimir P. Fedin
(R)- and (S)- enantiomers of alkyl aryl sulfoxides can be obtained by chromatographic resolution of the racemic mixtures of the sulfoxides on a microporous homochiral Zn-organic polymer or by simultaneous catalytic oxidation of the corresponding sulfides with H2O2 and enantioselective chromatographic resolution of the resulting sulfoxides in a one-pot process.