Determination of Electroactive Surface Area of Ni‑, Co‑, Fe‑, and Ir-Based Oxide Electrocatalysts
journal contributionposted on 2019-09-13, 12:06 authored by Sebastian Watzele, Pascal Hauenstein, Yunchang Liang, Song Xue, Johannes Fichtner, Batyr Garlyyev, Daniel Scieszka, Fabien Claudel, Frédéric Maillard, Aliaksandr S. Bandarenka
Metal oxides are important functional materials with a wide range of applications, especially in the field of electrocatalysis. However, quick and accurate assessment of their real electroactive surface area (ECSA), which is of paramount importance for the evaluation of their performance, remains a challenging task. Herein, we present a relatively simple strategy for an accurate in situ determination of the ECSA of commonly used metal oxide catalysts, namely Ni-, Co-, Fe-, Pt-, and Ir-based oxides. Similar to the well-established practice in electrocatalysis, the method is based on the phenomenon of specific adsorption. It uses the fact that at electrode potentials close to the onset of the oxygen evolution reaction, specifically adsorbed reaction intermediates manifest themselves through so called adsorption capacitance, which is unambiguously detectable using electrochemical impedance spectroscopy. We determined and calibrated these capacitances for common catalyst metal oxides using model thin films. Therefore, with simple impedance measurements, experimentalists can acquire the adsorption capacitance values and accurately estimate the real electroactive surface area of the above-mentioned oxide materials, including nanostructured electrocatalysts. Additionally, as illustrative examples, we demonstrate the application of the method for the determination of the ECSA of oxide catalyst nanoparticles.
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electrochemical impedance spectroscopyIr-based oxidesadsorption capacitanceelectrode potentialsECSAIr-Based Oxide Electrocatalysts Metal oxidesoxygen evolution reactionoxide materialsreaction intermediatesElectroactive Surface Areaimpedance measurementsnanostructured electrocatalystsmetal oxide catalystsadsorption capacitance valuesoxide catalyst nanoparticleselectroactive surface areacatalyst metal oxides