Centrifugal-Coated Quasi-Two-Dimensional Perovskite CsPb2Br5 Films for Efficient and Stable Light-Emitting Diodes
journal contributionposted on 20.10.2017, 00:00 by Chuanjiang Qin, Toshinori Matsushima, Atula S. D. Sandanayaka, Youichi Tsuchiya, Chihaya Adachi
The optical, structural, and electroluminescent (EL) characteristics of pure quasi-2D CsPb2Br5 were reported. We fabricated continuous, compact, well-crystallized CsPb2Br5 films by centrifugal coating from a colloidal solution containing CsPb2Br5 nanoparticles. The centrifugal-coated CsPb2Br5 films have a photoluminescence quantum yield (PLQY) of ∼35% because of its low-dimensional structure. Taking advantage of the high PLQY, we fabricated perovskite light-emitting diodes (PeLEDs) with a centrifugal-coated CsPb2Br5 emitting layer exhibiting bright green EL, a maximum luminance of 7317 cd m–2, an and external quantum efficiency of 1.1%. Additionally, the EL color could be changed easily from green to red using a halogen exchange method. The half lifetime of our CsPb2Br5 PeLEDs reached around 6 h under continuous operation at 10 mA cm–2.
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Stable Light-Emitting Diodescentrifugal-coated CsPb 2 Br 5 filmsphotoluminescence quantumperovskite light-emitting diodeshalogen exchange methodquantum efficiencyPLQYcentrifugal-coated CsPb 2 Br 5low-dimensional structurequasi -2D CsPb 2 Br 5CsPb 2 Br 5 PeLEDswell-crystallized CsPb 2 Br 5 filmsCsPb 2 Br 5 nanoparticlesEL colorhalf lifetime6 hCentrifugal-Coated Quasi-Two-Dimensional Perovskite CsPb 2 Br 5 Films