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A Novel Approach to the CDE Ring System of Pectenotoxin-4 Triggered by VO(acac)2-Induced Epoxy-Acetalization

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journal contribution
posted on 2009-02-05, 00:00 authored by Sarah Carley, Margaret A. Brimble
A novel approach to the CDE fragment of pectenotoxin-4 is described wherein the bicyclic acetal is constructed via a cascade cyclization induced by VO(acac)2 epoxidation of a homoallylic alcohol.