Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands
journal contributionposted on 17.01.2017 by Andrew Brown, Mohamed Saber, Willem Van den Heuvel, Kelsey Schulte, Alessandro Soncini, Kim R. Dunbar
Any type of content formally published in an academic journal, usually following a peer-review process.
The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.