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Stereospecific Iron-Catalyzed Carbon(sp2)–Carbon(sp3) Cross-Coupling with Alkyllithium and Alkenyl Iodides

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journal contribution
posted on 12.03.2019, 13:10 by Xiao-Lin Lu, Mark Shannon, Xiao-Shui Peng, Henry N. C. Wong
An efficient synthetic protocol involving iron-catalyzed cross-coupling reactions between organolithium compounds and alkenyl iodides as key coupling partners was achieved. More than 30 examples were obtained with moderate to good yields and high stereospecificity. Gram-scale and synthetic applications of this procedure are recorded herein to demonstrate its feasibility and potential utilization.

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