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One polynuclear copper(II) complex based on salicylaldehyde phenoxyacylhydrazone: structural and magnetic studies

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journal contribution
posted on 30.01.2015 by Xiaohua Chen, Shixiong Liu, Qiongjie Wu

One new copper(II) complex with a multidentate Schiff-base ligand salicylaldehyde phenoxyacylhydrazone (H2L), {[Cu4(L)4(DMF)]·DMF}n (1) has been synthesized and structurally characterized. Complex 1 exhibits a coordination polymer with a 1-D infinite chain-like structure, resulting from the Cu(II) centers linked by N–N single bonds. Magnetic behavior of 1 shows that it is antiferromagnetic.