<b>Absolute asymmetric synthesis of a homochiral polymer from an achiral monomer</b>

<p dir="ltr">The present work discusses about the absolute asymmetric synthesis of homochiral polymer from achiral monomers via topochemical reactions.</p><p dir="ltr">Mono fid folder has all the monomer nmr data corresponding to Supplementary Fig. 7 to Supplementary Fig. 11</p><p dir="ltr">fid file 70 c folder has all the temperature-dependent nmr data at 70 C corresponding to Fig. 2a in manuscript</p><p dir="ltr">100 c fid folder has all the temperature-dependent nmr data at 100 C corresponding to Fig. 2b in manuscript</p><p dir="ltr">IR text folder has all the temperature-dependent ir data at 70 C corresponding to Fig. 2c in manuscript</p><p dir="ltr">fid solid-state folder has all the solid-state data of monomer and polymer correspoonding to Fig.2d in the manuscript</p><p dir="ltr">PXRD mono only folder corresponds to fig. 3b in manuscript</p><p dir="ltr">PXRD kinetics text folder corresponds to fig. 3c in manuscript</p><p dir="ltr">fid 120 c folder corresponds to Supplementary Fig. 3 in SI</p><p dir="ltr">63-fid folder corresponds to Supplementary Fig to 16-18</p><p dir="ltr">Dx-67-poly gpc corresponds to Fig. 3a in manuscript</p>