ja9b10919_si_003.cif (10.81 kB)

Trilayered Lead Chloride Perovskite Ferroelectric Affording Self-Powered Visible-Blind Ultraviolet Photodetection with Large Zero-Bias Photocurrent

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posted on 26.12.2019 by Sasa Wang, Lina Li, Wen Weng, Chengmin Ji, Xitao Liu, Zhihua Sun, Wenxiong Lin, Maochun Hong, Junhua Luo
Perovskite ferroelectrics, in which the spontaneous polarization (Ps) is conducive to the separation of photoexcited charge carriers, have shown great potential for self-powered photodetection. Nevertheless, such self-powered ferroelectric photodetectors are mostly dominated by traditional inorganic oxides and exhibit relatively small zero-bias photocurrent, which limit their further application. Herein, we present a wide-bandgap 2D trilayered lead chloride hybrid perovskite ferroelectric, EA4Pb3Cl10 (1, EA = ethylammonium), which shows a notable Ps of ∼4.5 μC/cm2 and a high Curie temperature (415 K) beyond that of BaTiO3 (393 K). Significantly, benefiting from the wide bandgap of 3.39 eV, a self-powered visible-blind ultraviolet (UV) photodetector has been successfully realized, with a zero-bias photocurrent as high as 18.6 μA/cm2, which is nearly 2 orders of magnitude larger than those of mostly conventional inorganic ferroelectrics. As a pioneering study, this work offers an efficient approach for exploring wide-bandgap perovskite ferroelectrics and will excavate their application in the field of self-powered visible-blind UV photodetection.