Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands
datasetposted on 17.01.2017 by Andrew Brown, Mohamed Saber, Willem Van den Heuvel, Kelsey Schulte, Alessandro Soncini, Kim R. Dunbar
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The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.