Synthesis of Santiagonamine

Name: Synthesis of Santiagonamine
Published: 2007-08-16T00:00:00+00:00
License: https://creativecommons.org/licenses/by-nc/4.0/
Keywords: 12 steps, photocyclization, isovanillin, santiagonamine, Ullmann, Santiagonamine, Synthesi, synthesis

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posted on 2007-08-16, 00:00 authored by Michael D. Markey, Ying Fu, T. Ross Kelly

The first total synthesis of santiagonamine (1) is achieved in 12 steps from isovanillin. A palladium-catalyzed Ullmann cross-coupling reaction and a photocyclization are the key steps in the synthesis.

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12 steps photocyclization isovanillin santiagonamine Ullmann Santiagonamine Synthesi synthesis

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CC BY-NC 4.0

Synthesis of Santiagonamine

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