ja064609x_si_002.cif (29.43 kB)
Download file

Synthesis and Solution- and Solid-State Characterization of Gold(I) Rings with Short Au···Au Interactions. Spontaneous Resolution of a Gold(I) Complex

Download (29.43 kB)
posted on 04.10.2006, 00:00 authored by Andrea Deák, Tünde Megyes, Gábor Tárkányi, Péter Király, László Biczók, Gábor Pálinkás, Peter J. Stang
We report the synthesis and solution- and solid-state characterization of gold(I) rings with short 1,9-transannular Au···Au interactions. The 9- and 16-membered gold(I) rings were prepared by reacting 9,9-dimethyl-4,5-bis(diphenylphosphino)-xanthene and (Me2S)AuCl in the presence of AgNO3 in the molar ratio of 1:0.5:1 and 1:1:1, respectively. X-ray crystallographic measurements in conjunction with solution X-ray diffraction and NMR methods have been used to determine the structure of gold(I) rings, and we also gained insight into the dynamics. The nine-membered gold(I) ring is chiral, and the crystal contains only one of the two enantiomers, either right- or left-handed. To the best of our knowledge this represents the first example of crystallization-induced spontaneous resolution of a binuclear gold(I) cycle. The 16-membered ring with 1,9-transannular Au···Au interaction is in a figure-eight conformation.