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Solvent-Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2– Unit

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posted on 06.05.2013, 00:00 by Tatsunari Inoue, Katsunori Yamanishi, Mitsuru Kondo
A new 2D coordination polymer consisting of CuII ions, bis-imidazole-type ligands, and CO32– was prepared. This compound converted to new pentanuclear complexes with cyclic frameworks, which trapped a kinetically labile [Cu­(CO3)2]2– unit, by recrystallization from MeOH/Et2O or EtOH/Et2O.