Rational Synthesis of A2B-type meso-Triarylsubporphyrins
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posted on 2012-06-01, 00:00 authored by Takayuki Tanaka, Masaaki Kitano, Shin-ya Hayashi, Naoki Aratani, Atsuhiro OsukaRational synthesis of A2B-type meso-arylsubporphyrins has been accomplished by the condensation of triethylamine–tri-N-tripyrromethene–borane with acid chlorides. These subporphyrins are useful for evaluations of the intrinsic substituent effects and the influences of substitution patterns, A3-type versus A2B-type substitution.
