jo8b00650_si_003.cif (312.96 kB)
Download file

Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate

Download (312.96 kB)
posted on 16.04.2018, 00:00 by Zhiwei Xiao, Yongan Liu, Liping Zheng, Chao Liu, Yong Guo, Qing-Yun Chen
An efficient oxidative radical intermolecular trifluoromethylthioarylation of styrenes with arenediazonium salts and copper­(I) trifluoromethylthiolate under mild conditions is described for the first time. The reactions provide good yields of the corresponding trifluoromethylthioarylation products with broad substrate scope and excellent functional group compatibility.