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Oxidative Radical Intermolecular Trifluoromethylthioarylation of Styrenes by Arenediazonium Salts and Copper(I) Trifluoromethylthiolate

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posted on 16.04.2018, 00:00 by Zhiwei Xiao, Yongan Liu, Liping Zheng, Chao Liu, Yong Guo, Qing-Yun Chen
An efficient oxidative radical intermolecular trifluoromethylthioarylation of styrenes with arenediazonium salts and copper­(I) trifluoromethylthiolate under mild conditions is described for the first time. The reactions provide good yields of the corresponding trifluoromethylthioarylation products with broad substrate scope and excellent functional group compatibility.

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